Acetonitrile­[2-({bis[2,4,6-tris­(trifluorido­meth­yl)phen­yl]phosphan­yloxy}meth­yl)pyridine]­meth­ylpalladium(II) hexa­fluoro­anti­monate dichloro­methane hemisolvate

摘要

In the title compound, [Pd(CH3)(C24H10F18NOP)(CH3CN)][SbF6]·0.5CH2Cl2, the PdII atom has a distorted square-planar environment being coordinated by an acetonitrile N atom [Pd—N = 2.079 (3) Å], a methyl C atom [Pd—C = 2.047 (4) Å] and the bidentate ligand 2-({[2,4,6-tris­(trifluoro­meth­yl)phen­yl]phosphan­yloxy}meth­yl)pyridine (L). In L, the short distance of 3.621 (3) Å between the centroids of pyridine and benzene rings indicates the presence of a π–π inter­action. The crystal packing exhibits weak inter­molecular C—H⋯F contacts. The solvent mol­ecule has been treated as disordered between two positions of equal occupancy related by an inversion center.